Crna cv examples
Destiny Reddit
2012.12.06 03:28 Cozmo23 Destiny Reddit
Welcome to Destiny Reddit! This sub is for discussing Bungie's Destiny 2 and its predecessor, Destiny. Please read the sidebar rules and be sure to search for your question before posting.
2011.03.13 16:32 DrJulianBashir /r/ScenesFromAHat, where everything's made up and the points don't matter
Welcome to the official unofficial community for the game Scenes from a Hat, as played in the popular improv comedy show "Whose Line Is It Anyway?" Create hilarious scene responses to some recent prompts, or post new scenes and see what the community can deliver! Just make sure to create a scene with your response; Reddit has enough of that from AskReddit ! For a sample of how the game is played, check this video: https://youtu.be/aJQ75U4JGgM Also, make sure to check the rules. Bzzzzzzzzz!
2018.06.29 21:46 xX_WhatsTheGeek_Xx The official MichaelReeves subreddit
This is the official Michael Reeves subreddit, run by his discord admins and friends. He is a professional dipshit who makes projects involving computers and robotics, and is a member of OfflineTV. Michael Reeves Discord Server: https://discord.gg/mdVS2Cv
2024.05.19 16:18 Radiant-Hope-469 Charlotte Corday (Caster)'s Servant Profile from F/GO Material XIV
Charlotte Corday
Class: Caster True Name: Charlotte Corday Gender: Female Source: History Region: France Alignment: Chaotic Summer Height: 166 cm Weight: 43 kg Strength: E Endurance: E Agility: D Mana: C++ Luck: A Noble Phantasm: AScenario Writer: Yuuichirou Higashide Character Design: Takao Aotsuki CV: Yui Horie Main Appearance: Fate/Grand Order
○ Class Skills
Magic Show Field: EX A variation on Territory Creation. Corday constructs an environment suitable for performing stage magic. It also helps make up for her lack of technical skill.
Create Magic Goods: C+ A variation on Item Construction. The higher this skill's rank, the more things one can instantly create to aid with her stage magic. However, as Corday is still learning the basics of being a stage magician, she can only make items for interpersonal use.
○ Personal Skills
Illusionist (Imposter): C+ An illusion that relies on pure skill rather than magecraft. Occasionally, a truly talented practitioner will acquire the Genuine version. This skill shows its targets, and sometimes experience, things that can't be seen, or even cannot possibly be real. Of course, since Corday basically fell into being a stage magician, her skills pale in comparison to other, more talented Heroic Spirits of this sort.
Haphazard Show Planning: A Even when Corday cobbles her shows together with practically nothing in the way of planning, they tend to go great for some reason. The audience finds itself willing to overlook a few mistakes, and generally goes home satisfied.
Stage Magician Angel: EX Corday's...mysterious angel friend compensates for any mistakes she might make. Really, when you think about it, this angel is the strangest part of all of this.... The angel can lower the audience's guard, enhance their suspension of disbelief, and keep them entertained...and scarily enough, it can do those things just as well in battle too.
○ Noble Phantasm To Be Applauded Would Be a Dream Come True: La Féerie d'une Nuit Rank: C++ NP Type: Anti-Personnel Range: 1 Maximum Targets: 100
La Féerie d'une Nuit. A magic show that combines illusion with offense. Usually, Corday's rudimentary technique would only enable this NP to achieve D-rank destruction and E-rank illusions. However, when combined with her skills, it's possible for it to become a truly fearsome attack.
○ Character First person pronoun: watashi Second person pronoun: anata Third person pronoun: Kare/kanojo/ano kata
○ Personality Despite changing her class from Assassin to Caster, there hasn't been much change. She's still full steam ahead on the path of a maiden.
○ Motives and attitude towards Master She's trying to conceal her affection but is failing miserably at it.
○ Example lines “Step right up! It's time for a Corday magic show! I hope my auDIEnce will enjoy it!” (Not a typo) “With a whoosh…Dragon's Splitting Scale! Oh no!” “Now then everyone, please give a round of applause!”
○ Character Portrayal in Fate/GO A 2021 swimsuit Servant. Though still somewhat embarrassed by how much attention her new swimsuit draws, Corday has decided that this summer will be the one where she makes her move on Master.
Her personality may not have changed much, but now that she's no longer scared of rejection, she's also being more aggressive, which has led some Servants to be extremely wary of her.
She learned how to do stage magic from a shady, dapper old bartender, and a mysterious centaur sage.
○Normal Weapons Various magic goods.
○Connection to other Characters
Swimsuit Princess “I don't think pranks and magic are really the same thing... But isn't it a bit too flashy for a princess?” “‘What, I'm quite similar too?’ ... Well, never mind about me! I mean, I'm just an ordinary person!”
Japanese Princess with Strong Opinions on Villainess Stories “‘Standing next to the princess, I look like the protagonist of a villainess story?’ That just makes me look like a villain, no way!”
Suspicious Bartender “Thank you for teaching me magic tricks! Look, now I can... um... I can do this! Ah, wait! I almost got it!” (※ Not actually able to do it)
Not-so Suspicious Centaur “Thank you for teaching me techniques to captivate the audience. Psychology is amazing!”
Comment from Illustrator Since it's Corday in a swimsuit, I drew with the concept of wanting to show skin whenever possible. Looking back, I realized that there were quite a few expressions I made that I didn't use, and I wish I had included some more blushing ones. (Takao Aotsuki)
2024.05.19 11:58 Pistolfist Can Dehya have too much HP?
I FINALLY got Dehya during Arlecchinos banner and have just got round to building her.
I'm not building her for DPS or reactions, but any additional DPS she can provide is nice to have. I'm building her mainly for my lyney comp, or in any comp that wants a pyro damage and stagger mitigation unit since I find Thoma awful and Xinyan underwhelming.
I've got my Dehya to 61k HP and she does her job wonderfully, what I'm wondering is, would she be doing the job just as well if I had for example 50k hp and invested a bit more into CV/ATK?
Is there a diminishing return point or even a cap on what mitigation she can provide with her HP or is the sky the limit?
submitted by Pistolfist to Dehyamains [link] [comments]
I'm not building her for DPS or reactions, but any additional DPS she can provide is nice to have. I'm building her mainly for my lyney comp, or in any comp that wants a pyro damage and stagger mitigation unit since I find Thoma awful and Xinyan underwhelming.
I've got my Dehya to 61k HP and she does her job wonderfully, what I'm wondering is, would she be doing the job just as well if I had for example 50k hp and invested a bit more into CV/ATK?
Is there a diminishing return point or even a cap on what mitigation she can provide with her HP or is the sky the limit?
2024.05.19 06:10 bye2_lilsebastian How would you feel if you received a "graphical" bidding resume? Obviously no photos or over the top colors/fonts etc
I've seen fascinating bidding resumes from colleagues who obviously ensure the content is priority but are also clearly talented design-wise, and I found them refreshing and pleasantly surprising amid a stack of static, cookie-cutter resumes. Regardless of the cone/speciality, how would you feel if you received a "graphical" bidding resume?
12 Examples:
View Poll
submitted by bye2_lilsebastian to foreignservice [link] [comments]
12 Examples:
View Poll
2024.05.19 02:11 Due-Cut5858 How to add impact of work done under Work Experience as an iOS app developer
I have come across many suggestions that you have to add impact of your work under work experience, for example, "Developed an interface that increased user by 97%" or "improved user's efficiency by 80%", etc.
The company I work in as an iOS developer gives us UX guide and features to include in current release, etc. And my job is to develop the feature accordingly. The work I do should have little significance on users since I'm just the developer and I have no way to actually measure anything on the user. How should I put my impact on my CV in this case? Is this really needed? If not, how should the work experience look like?
submitted by Due-Cut5858 to resumes [link] [comments]
The company I work in as an iOS developer gives us UX guide and features to include in current release, etc. And my job is to develop the feature accordingly. The work I do should have little significance on users since I'm just the developer and I have no way to actually measure anything on the user. How should I put my impact on my CV in this case? Is this really needed? If not, how should the work experience look like?
2024.05.19 00:58 SansIdee_pseudo The Cheng is the new Amanar (and other "master level" skills that were replaced by another over the years)
From 2006 to 2016, the Amanar was seen as the "master level" vault to do to be considered a great vaulter. However, it has been downgraded and as a result, the "master level" to do now is the Cheng. The first flight phase is a bit more complicated, but the second flight phase is not a blind landing and has one less twist. Nowadays, doing an Amanar compared to a dty is not worth it.
Another example of that is the overshoot to handstand on bars. Up to 2012, the overshoot to handstand was very popular because you could connect it to a C element back to the high bar and get an easy 0.1 in CV. However, the formula in 2013 was deleted and as a result, the Pak salto + shaposh type skill became the more popular combination to earn CV. As a result, the overshoot to handstand is pretty much only perfomed in NCAA nowadays. I could add the Markelov and the giant 3/2, who was quite popular among top bar workers in 2001-2004, but fell out of popularity after the new scoring system.
On beam, it's hard to think of any skill in particular.
on floor, perhaps, the cat leaps and the tuck jumps 2/1 were very popular in 2001-2004 because you needed to do those dance combos to earn a 10.0 SV, but with the new scoring system, it's not worth doing those skills anymore.
Do you have other examples?
submitted by SansIdee_pseudo to Gymnastics [link] [comments]
Another example of that is the overshoot to handstand on bars. Up to 2012, the overshoot to handstand was very popular because you could connect it to a C element back to the high bar and get an easy 0.1 in CV. However, the formula in 2013 was deleted and as a result, the Pak salto + shaposh type skill became the more popular combination to earn CV. As a result, the overshoot to handstand is pretty much only perfomed in NCAA nowadays. I could add the Markelov and the giant 3/2, who was quite popular among top bar workers in 2001-2004, but fell out of popularity after the new scoring system.
On beam, it's hard to think of any skill in particular.
on floor, perhaps, the cat leaps and the tuck jumps 2/1 were very popular in 2001-2004 because you needed to do those dance combos to earn a 10.0 SV, but with the new scoring system, it's not worth doing those skills anymore.
Do you have other examples?
2024.05.19 00:36 Glibbins Is it ever worth buying the most expensive taps or shower heads?
For example, you can get a shower head that does the same thing but one costs almost 10x the price.
Such as this vs the cheaper one
What is so much better about the first one that it costs so much more? Could you ever justify paying that price or even half as much?
submitted by Glibbins to AusRenovation [link] [comments]
Such as this vs the cheaper one
What is so much better about the first one that it costs so much more? Could you ever justify paying that price or even half as much?
2024.05.18 16:52 nomoresportydates Is it normal for a dentist to ask me to demonstrate my hand skills before writing a rec letter?
I asked the general dentist that I’ve been shadowing for the past two months if he could write me a rec letter and he very enthusiastically agreed to write one. He said I had great rapport with patients, a stellar academic record, and an impressive CV. However, he didn’t feel totally comfortable recommending me without knowing how good my hand skills were. He asked me for examples of my hand skills and I shared some of my research lab/mice handling experience with him (but that was “too academic” for him). I even shared some of my personal hobbies like playing the violin and watercolor but that wasn’t what he was looking for.
He told me that when his father interviewed for dental school, he had been asked to carve a sphere out of a bar of soap and he wants to include something impressive like that in my letter in order to “hype me more.” He was pretty insistent about setting up a last minute meeting for me to complete this until I shared that I was out of town and unable to do so. He dropped it and agreed to highlight my other strengths instead. Is this normal?? Should I be worried about him saying something backhanded about not knowing how good my hand skills are in the letter??
submitted by nomoresportydates to predental [link] [comments]
He told me that when his father interviewed for dental school, he had been asked to carve a sphere out of a bar of soap and he wants to include something impressive like that in my letter in order to “hype me more.” He was pretty insistent about setting up a last minute meeting for me to complete this until I shared that I was out of town and unable to do so. He dropped it and agreed to highlight my other strengths instead. Is this normal?? Should I be worried about him saying something backhanded about not knowing how good my hand skills are in the letter??
2024.05.18 16:16 scifihiker7091 How to roast your own resume - tutorial
I probably spent over an hour roasting a resume yesterday. Someone then commented that they would post their resume on here to be roasted if they knew they could get detailed feedback like that. Unfortunately, I do one of these deep dives only about once or twice a month so I thought I’d share some tips on how to self-roast your resume. I’m also opening this post up to discussion for others to share their own tips on how to create more effective resumes, so hit the reply button and share your brilliance.
Here’s a few tips to get things started.
submitted by scifihiker7091 to FPandA [link] [comments]
Here’s a few tips to get things started.
- The hardest thing for people to remember when updating their resume is that the bullets for their previous job(s) should all be in the past tense. I’ve seen resumes on here where every job bullet was in the present tense. Anal retentive hiring managers will notice and it can be a distraction during their review of your CV.
- Read the review comments from recent resume roasts for suggestions and ideas to make your resume better. Sometimes an oddball resume format may cause you to reexamine your preconceived notions of what an effective resume looks like: for example, you can write an effective resume that’s more than a page long but unless you have off the charts work experiences to sell and have above average writing skills, the one page format is your friend for 85% of candidates.
- How do you read all the recent resume roasts without slogging through a gazillion other posts on this sub? The easiest way is to go to your internet browser, not the mobile app, and to search old.reddit. Copy and past this to your browser and it should save you some time:
- Start commenting on others’s resumes submitted for roasting. A lot of what I do in roasting a resume is noticing errors that the author is too blind to see because it’s their baby and no one wants to admit that their baby has warts. It’s actually a psychological roadblock called a scotoma where you believe nothing is wrong and therefore don’t see the glaring errors apparent to everyone else. The more you review and notice the errors in others’s resumes the more you will become immune to this limitation.
- If something makes you stand out from other candidates, include it at the top of your resume. If it makes you appear less than other candidates, push it to the bottom. For example, it would be idiotic not to include both a summary section and education section at the top if you did your MBA at a top tier graduate school and worked at a FAANG (MAANG) several jobs ago. If you only have a non-finance bachelor’s degree, put education at the bottom of the resume: otherwise, you may be eliminated by a hiring manager before they’ve even read your work experience. They may still reject you for this; however, at least they have the complete mosaic of you before reaching that conclusion.
- Most accomplishment bullets should be one sentence long and no more than two lines of text.
- Projects deserve more length to adequately tell the story. Take 3-4 sentences and no more than three lines of text to convey the problem/opportunity, the other teams involved, your specific contribution, and the outcome achieved preferably in quantifiable metrics (15% reduction in office supplies expense).
- If you don’t have any accomplishments on your resume that include quantitative metrics ($25M, 17%), you are at a competitive disadvantage compared to other candidates who do.
- Read your resume out loud. Maybe not from your cubicle on in office days, but find someplace quiet at home and listen to how the phrasing sounds to your ear. Some people write in an overly formal manner when fewer gargantuan words would serve them better. Speaking your resume out loud can catch errors or poor word choice that may otherwise go undetected from a visual reading.
2024.05.18 12:06 DragonfruitFancy595 Talking about experience which are not mentioned in the CV.
What if I want to share a critical achievement or experience that is not mentioned in my CV. Due to current trend of tailoring CV, I had omitted many relevant parts to elaborate on the the skills/experience that matched the JD. Now I can think of solid examples from my past experience that I would like to use in my interview answers. I am wondering if I could use those achievements/experience or should just only focus on what I have written in the submitted resume.
the omitted achievement was regarding process improvement which I really believe to be a great talking point for the interview.
submitted by DragonfruitFancy595 to interviews [link] [comments]
the omitted achievement was regarding process improvement which I really believe to be a great talking point for the interview.
2024.05.18 10:57 Successful_Day_4547 Looking Ahead - Job Market
Hi All,
I'd like to start a discussion on the steps we can take to be prepared for when the job market eventually improves.
I know it depends a lot on each individual situation but I hope we get some ideas that would apply for anyone in this sub or at least for most people.
I want to be better prepared to seize good opportunities in the future when the job market improves, and I hope this discussion is valuable for others as well.
submitted by Successful_Day_4547 to DevelEire [link] [comments]
I'd like to start a discussion on the steps we can take to be prepared for when the job market eventually improves.
I know it depends a lot on each individual situation but I hope we get some ideas that would apply for anyone in this sub or at least for most people.
- What should we be doing now to be in a better position when things improve?
I want to be better prepared to seize good opportunities in the future when the job market improves, and I hope this discussion is valuable for others as well.
2024.05.18 06:24 LucyAriaRose New Updates: He (42m) is so jealous of our kids and it’s starting to scare me (35f). Is this family and marriage even savable?
I am still NOT the Original Poster. That is u/ThrowRA-scarecrow. She posted in relationship_advice. Thank you to u/Direct-Caterpillar77 for the original recommendation and to u/ivy5kin for letting me know about the update
Previous BORU here. New Updates (starting with one from a few months ago and ending with one 7 days old) marked with ****\*
Mood Spoiler: utterly terrifying and disturbing
Original Post: March 16, 2024
My husband (42m) and I (35f) tried for so long to have our boys and girl. Due to a health issue my husband suffered he developed fertility issues and we had to get medical assistance to be able to have our children because if we didn’t he’d probably never have kids. So we went through fertility treatment. He desperately wanted his own biological children and we spent a fortune just to bring them into the world and now he’s jealous and distant with them?
He’s constantly in competition with his own infant children. If I hold the children he gets frustrated. Any time they take my attention away he gets completely pissy. He’s always in a foul mood, irritable and just down right nasty. I don’t understand it. Why is he like this? Our children are barely 6 months and they won’t stop crying every time he’s near. I feel like they can sense his negativity. I tried talking to him. Ive suggested he take interest in the kids and spend more time with us as a family. I know it can sometimes take a little longer for parents to bond with their children but this is down right scary to experience. He’s full of jealousy and envy. He sees our children as competition to my time and affections.
A few times now he has made comments about feeling frustrated that I still breast feed our children. The thing is we mix feed so he has had ample opportunity to feed them and he just doesn’t. He also said that this (meaning our life&our marriage after children) wasn’t what he thought it would be like. I mean what did he expect? A singular baby cries and three of them cry a lot.
We’ve been together for 8 years and married for 7 years. He wanted these children. He pushed for them and now this. I never thought this would ever be me. I am scared. I am scared for my children. I have tried talking to him but he just brushes me off. I’ve suggested counseling. He refuses. He tells me it’s all in my head. I want to save this marriage but I am scared I won’t be able to and maybe it’s not worth saving.
He comes home later everyday. He avoids us on the weekends and any time he has off. I’m not ashamed to say that I went through his phone and there are a lot flirtatious text between him and a “Jessica”. I don’t think anything has happened between them but it sure looks like they are building up to it. I haven’t said anything because I’m afraid. Where do I go with three children, with no money and no family that can help me? I haven’t worked in two years and I’ve spent all my savings on having these children. My mind is in a complete meltdown. I can’t sleep I can’t think and I’m always exhausted.
What the hell happened? Is this him now forever?
Edit: Some of you are some real evil bastards ! Stop blaming me for him mistreating me! I do not deserve to be treated this way and neither do my kids! Stop messaging me evil things!
Relevant Comments:
Examples of 'competition':
If I’m with the kids and say I’m feeding them he gets upset I’m focusing on them and not him, or as he likes to say I’m fussing over them. He expects they sleep through the night and gets upset when I’m with them instead of in bed with him. He has even made weird comments about me loving them more than him.
Did he really want kids or did YOU want kids?
Due to my husband’s fertility issues he was the one pushing for us to have kids. He knew early on that he had a health condition and wanted us to have children way earlier but I asked if we could wait but then his condition worsened so we agreed to get treatment before he couldn’t have any kids. He desperately wanted to be a father and they are biologically ours. His desire to be a father was one of the qualities I liked about him when we started dating.
I’ve always worked and the plan was for me to stay home for the first 2/3 years and perhaps work part time until the kids were school aged. But that’s out the window now because I don’t want to ever be this vulnerable! I’ve been brushing off my cv and scouring the internet for a job. I will never allow myself to be this vulnerable again.
Does he help at ALL? Do you have a support system you could go to?
He doesn’t help me at all. I take care of our kids on my own. My parents are long gone and my sister is abroad. She stayed with us for the birth and a month after the children were born. She lives in France but she’s due to return home this summer. So I know I’ll have her help when she’s back. But I’m trying not to bother her as she’s going through a divorce.
I’ve suggested couples counseling and he refuses. He says everything is in my head.
I’m actually even crying writing this but I do have a small to go bag in the trunk of my car. Just incase. I feel like I’m not being rational because he doesn’t hurt me or the kids but I feel like I’m constantly walking on eggshells. Like what happened to my happy go lucky husband? Who’s this person I’m afraid of?
Are they his biologically? Did you guys go to a support group for infertility treatment?
We didn’t use any sperm or egg donations. The kids are his and mine biologically.
We also went to a support group, two support groups actually. One of them was for couples and the other for men experiencing infertility. He also went to individual therapy to deal with his emotional issues around infertility.
Update Post: March 19, 2024 (3 days later)
Title: He’s (42m) been pinching my (35f) babies?
Thank you to the person who said I should watch his interactions with my babies more closely and frequently. Not even hours after I posted here asking for advice I caught him pinching my son!
While I was scrolling on here and replying to people I decided to check my baby monitor and I watched my husband enter our children’s room and insult them in a hushed and whispery tone. I couldn’t make out much of what he was saying but he was without a doubt telling them that he hated them and wished them dead. Then he pinched my son and my baby boy didn’t even cry which made me think he’s done this many times before.
It all happened so fast and by the time I could make sense of what was happening on the monitor he was already walking down the hallway and down the stairs. At the same time I had lept off the sofa and pretty much tackled him as he came off the stairs. We got into a physical and verbal altercation, we fought, argued and shouted for hours. I guess the police were called by the neighbors because the next thing I know the police are banging on my door. I explained the situation to the police and the officers said that they could not prove that my baby was harmed since he didn’t have a bruise and my baby monitor was only on live feed and not simultaneously recording. Eventually they got my husband to agree to pack a bag and leave. He left reluctantly.
He has since been blowing up my phone begging for forgiveness, talking about how he’s been depressed and stressed by the babies, and that his anxiety and jealousy got the best of him. I just responded once telling him to go fuck himself. I’ve also been in contact with a lawyer and she’s advised me to leave him unblocked incase he further incriminates himself. I don’t even recognize who this man is! Where did this all come from?
How did this happen? Has any other parent experienced this? How did you handle this?
Before y’all start jumping down my throat I am absolutely getting a divorce and I will do everything in my power to get full custody. I did take my children to our family doctor and they are in good health and there are no other signs of abuse. I’ve filled a report with the police and my lawyer is dealing with it. I’m also about to start the process of divorce.
Relevant Comments:
Commenter: He just wants more and better access to his victims. This is someone who gets off on hurting children. Actual human beings who are stressed and depressed do not sneak around abusing children for their dopamine hits.
I’ve set the monitor up to record now! I’ve also ordered a home security system and will be installing it real soon!
On what OOP is doing to protect them:
I’m doing everything I can to protect them! This all happened a few days ago but I am in the process of getting a temporary restraining order. My lawyer is handling it and I understand it takes some time to actually get one and in the meantime I’ve been advised that I can just deny him visitation until he gets a judgement from the courts that forces me to grant him access to my babies but that takes time. So in the meantime he can’t force me or my babies to see him.
I’ve recorded every call and saved ever text. Literally documenting everything. Thankfully he’s saying and texting a goldmine of incriminating things that I hope would be sufficient information for a judge to give me and my babies a restraining/protective order and for family court to grant me primary and sole custody.
Did you tell him you saw the pinch?
Yes. He at first told me I was imagining things. Then switched to saying he was just frustrated our son wouldn’t go to sleep. Then he started saying that he was angry that our son was interrupting our “personal time” and that he was doing it on purpose because the other babies were asleep so why wasn’t he?
Honestly nothing he says makes sense to me. Like my baby boy was just laying there sleepy and he would’ve fallen back to sleep by himself that bastard actually woke him up with his pinching and insults.
He says he went in their room to check up on them and I call bullshit on that he went in there to torment my children. Who in their right mind whispers death to two sleeping babies and a another half asleep baby?!
Did he tell you that over phone or text?
This was on a call which I’ve recorded!
*****Update Post 2: April 10, 2024 (3 weeks after OG post)****\*
Title: How did it go so wrong? For my (36f) birthday he (42m) broke into the house?
Every conversation with him (42m) feels like I’m (36f) losing my mind. The only thing that has kept me semi-sane and able to track what he has been doing is my audio journal and my posts on here.
Last week it was my thirty sixth birthday. Actually I had forgotten it was my birthday and was reminded by my sister that it was in fact my birthday. I decided I couldn’t mope around the house and I got my kids dressed to go shopping and get groceries. We got back and I put away half of the groceries but my babies were fussy and so to tire them out and ready them for bed we went for a walk. When I got back home he was in the kitchen cooking and putting away some of the groceries I had left out. He greeted me and acted normal. I didn’t react because his entire demeanour was freaking me out so I played along. I went upstairs and got the kids down. I did think of walking out the front door but he was kind of anticipating it and so he was following me around and I thought in the moment that the best thing I could do was to get my kids upstairs and away from him. He said he wanted to talk and clear the air because this has “gone on too long”.
We had a long conversation and it started out reasonable but eventually spiralled out of control. We got into physical confrontation because I refused to let him stay. He tried to physically intimidate me and he, well hurt me. While he was hurting me I was still able to contact the police. It took them a excruciatingly long 20/25 minutes to get there.
So here I am sitting with two completely black and blue eyes, a busted lip, swollen face,massive knots on my head and bruises all over. I don’t know what happened to my life or how I got here but here I am. I can’t even look my neighbors in the eyes. I can’t go outside without seeing the shocked faces of people.
I have never felt so ashamed, so humiliated, so hurt and so utterly stupid. I thought I made all the right choices in life. What did I do wrong? When did it all get so fucked? I mean I think I did everything right? Like I created a stable life for myself then picked a man that at time was a very loving partner, I married that man and waited five years before even going through the process of having children with him and now once I’ve had his children he’s just beating on me and our babies?
Edit: My sister is now aware of what’s been happening and she is supporting me as best as she can. I have plans to move out but since I’m not working right now I need some time to save up.
His family is also aware. His family refused to believe that I saw him hurt our child but they can’t deny this attack now that they’ve seen my bruises. Also yes he was arrested and he was bailed out by his brother. He’s currently staying with his brother.
Relevant Comments:
I’m in contact with a dv organization that my lawyer has put me in contact with. I did have a locksmith come out and I have new locks. I also have a couple of safety locks for my windows, and security cameras around the house and I changed our security code but honestly he doesn’t give a shit.
He despite it all broke in and beat the living shit out of me.
Making the audio journal:
I really didn’t make my audio journal to use as evidence. I literally made it because he makes me feel like I’m insane! I never know which version of him I’ll get at any given time. I also keep my journal to keep track of what he says. Every conversation with him makes me lose grip of my fleeting sanity.
Leaving the house:
The biggest reason I haven’t left my home is because he would without a doubt say I abducted the children! I’m already withholding my children from him since I caught him hurting my six month old son.
On advice of my lawyer I have stayed put. It’s my best option for now and it shows that I’ve been reasonably measured in my actions.
Restraining order?
I am in the process of getting one.
Update Post 3: April 25, 2024 (15 days later, almost 6 weeks from OG post)
Title: It was all for the love of another woman? Who barely knew of his existence? He (42m) hurt my (36f) children to further his own selfish desires
I say all of this without exaggeration. I am certain he was getting ready to kill us. After nearly 8 months of turmoil I’m finally close to understanding.
My soon to be ex husband is in love with a woman he came across on social media and he has been obsessing over her for at least a year. She also happens to be a sex worker and he was paying her for her time and attention. In his mind he believed they could have a future together if only he could get rid of my children and me. Even though this woman gave him no inkling that she even wanted to be with him. He has spent so much of our money on this woman. I am at a loss for words that could accurately describe the situation. I can barely believe half of the things he’s been up to.
I’ve spent the past few weeks playing detective and I finally decided to contact “Jessica”. This is obviously not her name but I need to call her something. I contacted Jessica and at first she was very reluctant to speak to me but I literally begged her to and she was kind enough to get on the phone with me.
She told me that she had been seeing him for awhile but she stopped seeing him because he started to scare her. He was sending her unhinged messages and voicemails. He had been stalking her and trying to convince her to be with him. Jessica eventually stopped seeing him and had him blocked and I guess this is when he started to escalate from emotional abuse to physically abusing my children and myself. He was looking for a way out and in his crazy mind, killing us would free him because the only reason Jessica wouldn’t be with him was because me and my children were in the way.
During our long call I also explained to Jessica what had been happening to me and she was genuinely kind and helpful. She also agreed to speak to my lawyer and to send them the thousands of unhinged texts, voicemails and voice notes he sent her. For a little while after our conversation a part of me genuinely hated Jessica and wanted to blame her for everything but the rational part of me pushed out those unreasonable and dangerous thoughts especially after I read his disturbing texts and heard his voicemail/notes to Jessica. She has also been victimized by him.
Honestly there is nothing like listening to your husband and father of your children talk about how you and your children mean nothing to him and how he wishes you were dead. He could’ve just asked for a divorce or just got up and left. I sent him a few texts asking him why? (this was a one time thing and since then I’ve stopped all contact) Why do all of this? Why torment my babies? Why not just walk away? He responded with a message saying any conversation between us should be through our lawyers. His parents have him lawyered up. They know what he’s been up to and they’ve chosen to protect him. His father came to see me and in a not so direct way suggested he could pay me if I stopped talking about what his son has done and was planning on doing. Ever since he broke into the house and pretty much tried to kill me I’ve told anyone who’d listen what he has done. At this point even his colleagues know.
Relevant Comments:
I have emergency custody of my kids and a protective order. I’m in the process of getting two trained guard dogs haven’t gotten very far though and I have a security system.
I’m also seriously considering a gun. More than seriously actually I’ve applied for a permit. Of course I do plan on taking lessons in gun safety and training.
Be careful with the dogs, he may just kill them:
He probably would but the few seconds to minutes he needs in order to do that is perhaps the chance I need to save my children and myself.
This may seem horrible to you but I rather have them as a buffer then my children getting harmed. I of course don’t want this to happen but I’m in a situation now where I need to do everything I can to protect my children.
His parents:
Oh they really are bastards and refuse to believe their precious son could ever do the things he’s done despite the fact that I installed security cameras after I caught him abusing my babies and despite the fact that my neighbors have signed witness statements attesting to the fact that they saw him break into my house and attack me. They’ve seen the police report. They’ve seen the pictures of my battered face and bruised body. They are feigning ignorance but they know, and I know they know.
You don't want to give him ammunition in the divorce- maybe stop telling people?
Actually me telling people has been the best thing I’ve done so far. It’s what has kept me safe. My neighbors now look out for his car and call the police if they see he’s anywhere near the house.
What was he like before all of this? Were there any signs?
We’ve been married for nearly 8 years. Will actually be 8 years in 2 months. We never had any issues. Sure we had minor squabbles but that was few and far in between. Never did I have any issues that would lead me to think that he’d try to hurt us let alone kill us.
It was during my pregnancy and birth that he became verbally and emotionally abusive, this is also the time period he met Jessica and started fantasizing about running away with her. He was angry and jealous that my attention was more on the pregnancy and the babies and this built resentment towards me and my children. It also pushed him more into his obsession with Jessica and when he was also rejected by her, he spiraled into this insane mindset. At the same time he escalated into verbally and physically abusing our infant children and when I found out he hurt my children, I attacked him. I caught him hurting my son and we physically fought and my neighbors called the police and he was escorted out of the house. Then he came back and broke into the house, he attacked me and beat me into a bloody mess. He was arrested for this. I’ve since attained a lawyer and I’ve been granted emergency custody and a protective order.
Again- why isn't he in jail?
He’s out on bail.
Update Post 3: May 11, 2024 (2+ weeks later)
Editor's note: This post was deleted by reddit. I have transcribed it from this youtube video and this tiktok video
Title: My (36f) husband (42m) has been arrested for stalking and attempting to abduct his former “mistress”.
Last week Thursday at approximately 2:00 AM in the morning, my (36F) husband (42m) of nearly 8 years was arrested outside of Jessica's house, (the sex worker he met online and used to pay to spend time with him until he started to creep her out by his stalking and obsession.)
When he was arrested, they found in his truck small baggies with drug residue and they also found tools of abduction. I honestly do not know what these are exactly.
My soon to be ex FIL called me at around 4:45/4:50 AM to tell me that his son was arrested. My FIL was the one who used the term tools of abduction. When I asked him what the hell that means, he said he didn't have time for my interrogation tactics. He then asked if I could help them find a lawyer for him and to stand by his son throughout all of this. When I said to him "how the hell am I supposed to find a lawyer this early in the morning," he lost his shit and then was just screaming.
My soon to be ex MIL took over the phone, telling me that I'm a goddamn b****, and that all this is my fault. I hung up before she could say anymore.
I never knew this man to take drugs. Sure, he drank occasionally, but hard drugs? I honestly don't know what's happening anymore or how I got here. I mean it does make sense he was on cocaine the past 7/8 months now that I look back at things.
I mean, I don't even know anything about drugs to be able to recognize the behavior pattern, but once I researched it, it seemed clear. The moodiness, the disappearances, the lies, the anger, the sudden outburst and the violence- it all points to drug usage, as well as him being an abusive piece of shit.
His parents and the rest of his family had called and texted me so much abusive shit and they occasionally switched to begging me to go see him or pick up his calls, but I've mainly ignored them. I don't have the time, the energy or the love that is needed to be there for this man and his parents. I've given him eight years of my love and affection, and he spat it back into my face during the hardest and most vulnerable time of my life
Also, why would they think I'd help him after everything he's done? Especially since I think he deserves to be in jail for not only hurting my children, but also for hurting myself and Jessica.
I hope and pray he's jailed for the rest of his natural life. I mean I've tried being a good wife, but he has attacked my children. He has attacked me. He has lied and tormented us, and I'm supposed to help him?
I don't even know how I got here. How did we get here?
I've packed everything up and I'm leaving. I'm disappearing with my kids, and anything else between me and these people can be handled through my lawyer. The only person who knows where I'm moving to is my lawyer and my sister. I mean what else can I do to protect my children? His entire family blames me. And how do I keep my head high when I'm now being treated like I'm an evil and disgusting person by pretty much everyone I once called a family? These people are trying to destroy me inside and out, and I don't know how to survive them. How am I supposed to rebuild my life when they won't stop tormenting me?
In less than a year of their birth, I've managed to fail my children...
TLDR: My soon to be ex-husband was arrested while stalking his former mistress/sex worker and during his arrest they found drug residue and tools for abduction
Relevant Comments:
Change your surname/the kids' surnames:
My kids and I have double-barreled surnames (my surname and their dads) but when I can we will drop his and we’ll all go by just mine.
People blaming OOP:
The sad fucking thing it’s not only his parents. It seems like everyone is blaming me.
OOP's response to a crappy (now deleted) comment:
“ You need to discover the reasons why you failed to notice or do anything about everything that was going on with him. You have to build skills so you can take full ownership over your own life.”
This genuinely has me fucking raging right now! I feel like everyone keeps blaming me!
And I don’t know why everyone keeps blaming me for his shit! We didn’t have any problems in the previous 7 years of our marriage. He started doing drugs during my pregnancy and this is when he started to behave abnormally. I tried to get him help because I thought it was depression or the stress of being a new parent.
When I noticed his irritablity, combativeness and generally shitty behavior was more than just depression or jealousy of me spending more time with my new born children, I kicked him out, I got a lawyer and involved the police because there no way in hell I’d stay with someone who hurt my children or let him get away with it and I also made sure to get emergency custody of my children. This is also around the same time when he spiralled into using more drugs. I don’t know what else I could’ve done but I know I took all the right steps when I noticed his escalation!
I’m so sick of everyone acting like I was making him do drugs and like I’m suppose to know that he’d ruin my life after having had a good marriage before he started taking drugs and going out of his mind.
What has your lawyer said about disappearing?
I currently have emergency custody. My lawyer is the one who suggested to disappear (meaning moving to new house and not letting anyone know) because she says this is a time of great danger and I heartily agree. Since my ex-husband first went to look for me at the house but me and my children went to stay somewhere else for a few days because I was scared he’d come back after he broke into the house previously and attacked me.
submitted by LucyAriaRose to BestofRedditorUpdates [link] [comments]
Previous BORU here. New Updates (starting with one from a few months ago and ending with one 7 days old) marked with ****\*
Read trigger warnings
Trigger Warnings: infant abuse; spousal abuse; drug use; stalking; kidnapping attemptMood Spoiler: utterly terrifying and disturbing
Original Post: March 16, 2024
My husband (42m) and I (35f) tried for so long to have our boys and girl. Due to a health issue my husband suffered he developed fertility issues and we had to get medical assistance to be able to have our children because if we didn’t he’d probably never have kids. So we went through fertility treatment. He desperately wanted his own biological children and we spent a fortune just to bring them into the world and now he’s jealous and distant with them?
He’s constantly in competition with his own infant children. If I hold the children he gets frustrated. Any time they take my attention away he gets completely pissy. He’s always in a foul mood, irritable and just down right nasty. I don’t understand it. Why is he like this? Our children are barely 6 months and they won’t stop crying every time he’s near. I feel like they can sense his negativity. I tried talking to him. Ive suggested he take interest in the kids and spend more time with us as a family. I know it can sometimes take a little longer for parents to bond with their children but this is down right scary to experience. He’s full of jealousy and envy. He sees our children as competition to my time and affections.
A few times now he has made comments about feeling frustrated that I still breast feed our children. The thing is we mix feed so he has had ample opportunity to feed them and he just doesn’t. He also said that this (meaning our life&our marriage after children) wasn’t what he thought it would be like. I mean what did he expect? A singular baby cries and three of them cry a lot.
We’ve been together for 8 years and married for 7 years. He wanted these children. He pushed for them and now this. I never thought this would ever be me. I am scared. I am scared for my children. I have tried talking to him but he just brushes me off. I’ve suggested counseling. He refuses. He tells me it’s all in my head. I want to save this marriage but I am scared I won’t be able to and maybe it’s not worth saving.
He comes home later everyday. He avoids us on the weekends and any time he has off. I’m not ashamed to say that I went through his phone and there are a lot flirtatious text between him and a “Jessica”. I don’t think anything has happened between them but it sure looks like they are building up to it. I haven’t said anything because I’m afraid. Where do I go with three children, with no money and no family that can help me? I haven’t worked in two years and I’ve spent all my savings on having these children. My mind is in a complete meltdown. I can’t sleep I can’t think and I’m always exhausted.
What the hell happened? Is this him now forever?
Edit: Some of you are some real evil bastards ! Stop blaming me for him mistreating me! I do not deserve to be treated this way and neither do my kids! Stop messaging me evil things!
Relevant Comments:
Examples of 'competition':
If I’m with the kids and say I’m feeding them he gets upset I’m focusing on them and not him, or as he likes to say I’m fussing over them. He expects they sleep through the night and gets upset when I’m with them instead of in bed with him. He has even made weird comments about me loving them more than him.
Did he really want kids or did YOU want kids?
Due to my husband’s fertility issues he was the one pushing for us to have kids. He knew early on that he had a health condition and wanted us to have children way earlier but I asked if we could wait but then his condition worsened so we agreed to get treatment before he couldn’t have any kids. He desperately wanted to be a father and they are biologically ours. His desire to be a father was one of the qualities I liked about him when we started dating.
I’ve always worked and the plan was for me to stay home for the first 2/3 years and perhaps work part time until the kids were school aged. But that’s out the window now because I don’t want to ever be this vulnerable! I’ve been brushing off my cv and scouring the internet for a job. I will never allow myself to be this vulnerable again.
Does he help at ALL? Do you have a support system you could go to?
He doesn’t help me at all. I take care of our kids on my own. My parents are long gone and my sister is abroad. She stayed with us for the birth and a month after the children were born. She lives in France but she’s due to return home this summer. So I know I’ll have her help when she’s back. But I’m trying not to bother her as she’s going through a divorce.
I’ve suggested couples counseling and he refuses. He says everything is in my head.
I’m actually even crying writing this but I do have a small to go bag in the trunk of my car. Just incase. I feel like I’m not being rational because he doesn’t hurt me or the kids but I feel like I’m constantly walking on eggshells. Like what happened to my happy go lucky husband? Who’s this person I’m afraid of?
Are they his biologically? Did you guys go to a support group for infertility treatment?
We didn’t use any sperm or egg donations. The kids are his and mine biologically.
We also went to a support group, two support groups actually. One of them was for couples and the other for men experiencing infertility. He also went to individual therapy to deal with his emotional issues around infertility.
Update Post: March 19, 2024 (3 days later)
Title: He’s (42m) been pinching my (35f) babies?
Thank you to the person who said I should watch his interactions with my babies more closely and frequently. Not even hours after I posted here asking for advice I caught him pinching my son!
While I was scrolling on here and replying to people I decided to check my baby monitor and I watched my husband enter our children’s room and insult them in a hushed and whispery tone. I couldn’t make out much of what he was saying but he was without a doubt telling them that he hated them and wished them dead. Then he pinched my son and my baby boy didn’t even cry which made me think he’s done this many times before.
It all happened so fast and by the time I could make sense of what was happening on the monitor he was already walking down the hallway and down the stairs. At the same time I had lept off the sofa and pretty much tackled him as he came off the stairs. We got into a physical and verbal altercation, we fought, argued and shouted for hours. I guess the police were called by the neighbors because the next thing I know the police are banging on my door. I explained the situation to the police and the officers said that they could not prove that my baby was harmed since he didn’t have a bruise and my baby monitor was only on live feed and not simultaneously recording. Eventually they got my husband to agree to pack a bag and leave. He left reluctantly.
He has since been blowing up my phone begging for forgiveness, talking about how he’s been depressed and stressed by the babies, and that his anxiety and jealousy got the best of him. I just responded once telling him to go fuck himself. I’ve also been in contact with a lawyer and she’s advised me to leave him unblocked incase he further incriminates himself. I don’t even recognize who this man is! Where did this all come from?
How did this happen? Has any other parent experienced this? How did you handle this?
Before y’all start jumping down my throat I am absolutely getting a divorce and I will do everything in my power to get full custody. I did take my children to our family doctor and they are in good health and there are no other signs of abuse. I’ve filled a report with the police and my lawyer is dealing with it. I’m also about to start the process of divorce.
Relevant Comments:
Commenter: He just wants more and better access to his victims. This is someone who gets off on hurting children. Actual human beings who are stressed and depressed do not sneak around abusing children for their dopamine hits.
OOP: Exactly! I’m tired, stressed, depressed and I’m physically still not fully healed from the pregnancy and the cesarean birth but not once have I thought of hurting anyone let alone a baby! I don’t buy his bullshit excuses. He clearly knew what he was doing was wrong otherwise he wouldn’t have been sneaking around and being all hush hush. I do not believe him for one second. He’s a goddamn beastly man.Update the monitor to one that records:
I’ve set the monitor up to record now! I’ve also ordered a home security system and will be installing it real soon!
On what OOP is doing to protect them:
I’m doing everything I can to protect them! This all happened a few days ago but I am in the process of getting a temporary restraining order. My lawyer is handling it and I understand it takes some time to actually get one and in the meantime I’ve been advised that I can just deny him visitation until he gets a judgement from the courts that forces me to grant him access to my babies but that takes time. So in the meantime he can’t force me or my babies to see him.
I’ve recorded every call and saved ever text. Literally documenting everything. Thankfully he’s saying and texting a goldmine of incriminating things that I hope would be sufficient information for a judge to give me and my babies a restraining/protective order and for family court to grant me primary and sole custody.
Did you tell him you saw the pinch?
Yes. He at first told me I was imagining things. Then switched to saying he was just frustrated our son wouldn’t go to sleep. Then he started saying that he was angry that our son was interrupting our “personal time” and that he was doing it on purpose because the other babies were asleep so why wasn’t he?
Honestly nothing he says makes sense to me. Like my baby boy was just laying there sleepy and he would’ve fallen back to sleep by himself that bastard actually woke him up with his pinching and insults.
He says he went in their room to check up on them and I call bullshit on that he went in there to torment my children. Who in their right mind whispers death to two sleeping babies and a another half asleep baby?!
Did he tell you that over phone or text?
This was on a call which I’ve recorded!
*****Update Post 2: April 10, 2024 (3 weeks after OG post)****\*
Title: How did it go so wrong? For my (36f) birthday he (42m) broke into the house?
Every conversation with him (42m) feels like I’m (36f) losing my mind. The only thing that has kept me semi-sane and able to track what he has been doing is my audio journal and my posts on here.
Last week it was my thirty sixth birthday. Actually I had forgotten it was my birthday and was reminded by my sister that it was in fact my birthday. I decided I couldn’t mope around the house and I got my kids dressed to go shopping and get groceries. We got back and I put away half of the groceries but my babies were fussy and so to tire them out and ready them for bed we went for a walk. When I got back home he was in the kitchen cooking and putting away some of the groceries I had left out. He greeted me and acted normal. I didn’t react because his entire demeanour was freaking me out so I played along. I went upstairs and got the kids down. I did think of walking out the front door but he was kind of anticipating it and so he was following me around and I thought in the moment that the best thing I could do was to get my kids upstairs and away from him. He said he wanted to talk and clear the air because this has “gone on too long”.
We had a long conversation and it started out reasonable but eventually spiralled out of control. We got into physical confrontation because I refused to let him stay. He tried to physically intimidate me and he, well hurt me. While he was hurting me I was still able to contact the police. It took them a excruciatingly long 20/25 minutes to get there.
So here I am sitting with two completely black and blue eyes, a busted lip, swollen face,massive knots on my head and bruises all over. I don’t know what happened to my life or how I got here but here I am. I can’t even look my neighbors in the eyes. I can’t go outside without seeing the shocked faces of people.
I have never felt so ashamed, so humiliated, so hurt and so utterly stupid. I thought I made all the right choices in life. What did I do wrong? When did it all get so fucked? I mean I think I did everything right? Like I created a stable life for myself then picked a man that at time was a very loving partner, I married that man and waited five years before even going through the process of having children with him and now once I’ve had his children he’s just beating on me and our babies?
Edit: My sister is now aware of what’s been happening and she is supporting me as best as she can. I have plans to move out but since I’m not working right now I need some time to save up.
His family is also aware. His family refused to believe that I saw him hurt our child but they can’t deny this attack now that they’ve seen my bruises. Also yes he was arrested and he was bailed out by his brother. He’s currently staying with his brother.
Relevant Comments:
I’m in contact with a dv organization that my lawyer has put me in contact with. I did have a locksmith come out and I have new locks. I also have a couple of safety locks for my windows, and security cameras around the house and I changed our security code but honestly he doesn’t give a shit.
He despite it all broke in and beat the living shit out of me.
Making the audio journal:
I really didn’t make my audio journal to use as evidence. I literally made it because he makes me feel like I’m insane! I never know which version of him I’ll get at any given time. I also keep my journal to keep track of what he says. Every conversation with him makes me lose grip of my fleeting sanity.
Leaving the house:
The biggest reason I haven’t left my home is because he would without a doubt say I abducted the children! I’m already withholding my children from him since I caught him hurting my six month old son.
On advice of my lawyer I have stayed put. It’s my best option for now and it shows that I’ve been reasonably measured in my actions.
Restraining order?
I am in the process of getting one.
Update Post 3: April 25, 2024 (15 days later, almost 6 weeks from OG post)
Title: It was all for the love of another woman? Who barely knew of his existence? He (42m) hurt my (36f) children to further his own selfish desires
I say all of this without exaggeration. I am certain he was getting ready to kill us. After nearly 8 months of turmoil I’m finally close to understanding.
My soon to be ex husband is in love with a woman he came across on social media and he has been obsessing over her for at least a year. She also happens to be a sex worker and he was paying her for her time and attention. In his mind he believed they could have a future together if only he could get rid of my children and me. Even though this woman gave him no inkling that she even wanted to be with him. He has spent so much of our money on this woman. I am at a loss for words that could accurately describe the situation. I can barely believe half of the things he’s been up to.
I’ve spent the past few weeks playing detective and I finally decided to contact “Jessica”. This is obviously not her name but I need to call her something. I contacted Jessica and at first she was very reluctant to speak to me but I literally begged her to and she was kind enough to get on the phone with me.
She told me that she had been seeing him for awhile but she stopped seeing him because he started to scare her. He was sending her unhinged messages and voicemails. He had been stalking her and trying to convince her to be with him. Jessica eventually stopped seeing him and had him blocked and I guess this is when he started to escalate from emotional abuse to physically abusing my children and myself. He was looking for a way out and in his crazy mind, killing us would free him because the only reason Jessica wouldn’t be with him was because me and my children were in the way.
During our long call I also explained to Jessica what had been happening to me and she was genuinely kind and helpful. She also agreed to speak to my lawyer and to send them the thousands of unhinged texts, voicemails and voice notes he sent her. For a little while after our conversation a part of me genuinely hated Jessica and wanted to blame her for everything but the rational part of me pushed out those unreasonable and dangerous thoughts especially after I read his disturbing texts and heard his voicemail/notes to Jessica. She has also been victimized by him.
Honestly there is nothing like listening to your husband and father of your children talk about how you and your children mean nothing to him and how he wishes you were dead. He could’ve just asked for a divorce or just got up and left. I sent him a few texts asking him why? (this was a one time thing and since then I’ve stopped all contact) Why do all of this? Why torment my babies? Why not just walk away? He responded with a message saying any conversation between us should be through our lawyers. His parents have him lawyered up. They know what he’s been up to and they’ve chosen to protect him. His father came to see me and in a not so direct way suggested he could pay me if I stopped talking about what his son has done and was planning on doing. Ever since he broke into the house and pretty much tried to kill me I’ve told anyone who’d listen what he has done. At this point even his colleagues know.
Relevant Comments:
I have emergency custody of my kids and a protective order. I’m in the process of getting two trained guard dogs haven’t gotten very far though and I have a security system.
I’m also seriously considering a gun. More than seriously actually I’ve applied for a permit. Of course I do plan on taking lessons in gun safety and training.
Be careful with the dogs, he may just kill them:
He probably would but the few seconds to minutes he needs in order to do that is perhaps the chance I need to save my children and myself.
This may seem horrible to you but I rather have them as a buffer then my children getting harmed. I of course don’t want this to happen but I’m in a situation now where I need to do everything I can to protect my children.
His parents:
Oh they really are bastards and refuse to believe their precious son could ever do the things he’s done despite the fact that I installed security cameras after I caught him abusing my babies and despite the fact that my neighbors have signed witness statements attesting to the fact that they saw him break into my house and attack me. They’ve seen the police report. They’ve seen the pictures of my battered face and bruised body. They are feigning ignorance but they know, and I know they know.
You don't want to give him ammunition in the divorce- maybe stop telling people?
Actually me telling people has been the best thing I’ve done so far. It’s what has kept me safe. My neighbors now look out for his car and call the police if they see he’s anywhere near the house.
What was he like before all of this? Were there any signs?
We’ve been married for nearly 8 years. Will actually be 8 years in 2 months. We never had any issues. Sure we had minor squabbles but that was few and far in between. Never did I have any issues that would lead me to think that he’d try to hurt us let alone kill us.
It was during my pregnancy and birth that he became verbally and emotionally abusive, this is also the time period he met Jessica and started fantasizing about running away with her. He was angry and jealous that my attention was more on the pregnancy and the babies and this built resentment towards me and my children. It also pushed him more into his obsession with Jessica and when he was also rejected by her, he spiraled into this insane mindset. At the same time he escalated into verbally and physically abusing our infant children and when I found out he hurt my children, I attacked him. I caught him hurting my son and we physically fought and my neighbors called the police and he was escorted out of the house. Then he came back and broke into the house, he attacked me and beat me into a bloody mess. He was arrested for this. I’ve since attained a lawyer and I’ve been granted emergency custody and a protective order.
Again- why isn't he in jail?
He’s out on bail.
Update Post 3: May 11, 2024 (2+ weeks later)
Editor's note: This post was deleted by reddit. I have transcribed it from this youtube video and this tiktok video
Title: My (36f) husband (42m) has been arrested for stalking and attempting to abduct his former “mistress”.
Last week Thursday at approximately 2:00 AM in the morning, my (36F) husband (42m) of nearly 8 years was arrested outside of Jessica's house, (the sex worker he met online and used to pay to spend time with him until he started to creep her out by his stalking and obsession.)
When he was arrested, they found in his truck small baggies with drug residue and they also found tools of abduction. I honestly do not know what these are exactly.
My soon to be ex FIL called me at around 4:45/4:50 AM to tell me that his son was arrested. My FIL was the one who used the term tools of abduction. When I asked him what the hell that means, he said he didn't have time for my interrogation tactics. He then asked if I could help them find a lawyer for him and to stand by his son throughout all of this. When I said to him "how the hell am I supposed to find a lawyer this early in the morning," he lost his shit and then was just screaming.
My soon to be ex MIL took over the phone, telling me that I'm a goddamn b****, and that all this is my fault. I hung up before she could say anymore.
I never knew this man to take drugs. Sure, he drank occasionally, but hard drugs? I honestly don't know what's happening anymore or how I got here. I mean it does make sense he was on cocaine the past 7/8 months now that I look back at things.
I mean, I don't even know anything about drugs to be able to recognize the behavior pattern, but once I researched it, it seemed clear. The moodiness, the disappearances, the lies, the anger, the sudden outburst and the violence- it all points to drug usage, as well as him being an abusive piece of shit.
His parents and the rest of his family had called and texted me so much abusive shit and they occasionally switched to begging me to go see him or pick up his calls, but I've mainly ignored them. I don't have the time, the energy or the love that is needed to be there for this man and his parents. I've given him eight years of my love and affection, and he spat it back into my face during the hardest and most vulnerable time of my life
Also, why would they think I'd help him after everything he's done? Especially since I think he deserves to be in jail for not only hurting my children, but also for hurting myself and Jessica.
I hope and pray he's jailed for the rest of his natural life. I mean I've tried being a good wife, but he has attacked my children. He has attacked me. He has lied and tormented us, and I'm supposed to help him?
I don't even know how I got here. How did we get here?
I've packed everything up and I'm leaving. I'm disappearing with my kids, and anything else between me and these people can be handled through my lawyer. The only person who knows where I'm moving to is my lawyer and my sister. I mean what else can I do to protect my children? His entire family blames me. And how do I keep my head high when I'm now being treated like I'm an evil and disgusting person by pretty much everyone I once called a family? These people are trying to destroy me inside and out, and I don't know how to survive them. How am I supposed to rebuild my life when they won't stop tormenting me?
In less than a year of their birth, I've managed to fail my children...
TLDR: My soon to be ex-husband was arrested while stalking his former mistress/sex worker and during his arrest they found drug residue and tools for abduction
Relevant Comments:
Change your surname/the kids' surnames:
My kids and I have double-barreled surnames (my surname and their dads) but when I can we will drop his and we’ll all go by just mine.
People blaming OOP:
The sad fucking thing it’s not only his parents. It seems like everyone is blaming me.
OOP's response to a crappy (now deleted) comment:
“ You need to discover the reasons why you failed to notice or do anything about everything that was going on with him. You have to build skills so you can take full ownership over your own life.”
This genuinely has me fucking raging right now! I feel like everyone keeps blaming me!
And I don’t know why everyone keeps blaming me for his shit! We didn’t have any problems in the previous 7 years of our marriage. He started doing drugs during my pregnancy and this is when he started to behave abnormally. I tried to get him help because I thought it was depression or the stress of being a new parent.
When I noticed his irritablity, combativeness and generally shitty behavior was more than just depression or jealousy of me spending more time with my new born children, I kicked him out, I got a lawyer and involved the police because there no way in hell I’d stay with someone who hurt my children or let him get away with it and I also made sure to get emergency custody of my children. This is also around the same time when he spiralled into using more drugs. I don’t know what else I could’ve done but I know I took all the right steps when I noticed his escalation!
I’m so sick of everyone acting like I was making him do drugs and like I’m suppose to know that he’d ruin my life after having had a good marriage before he started taking drugs and going out of his mind.
What has your lawyer said about disappearing?
I currently have emergency custody. My lawyer is the one who suggested to disappear (meaning moving to new house and not letting anyone know) because she says this is a time of great danger and I heartily agree. Since my ex-husband first went to look for me at the house but me and my children went to stay somewhere else for a few days because I was scared he’d come back after he broke into the house previously and attacked me.
2024.05.18 04:26 PerfecttMachine Cross validation Train/validation graphs [D]
A common trend for model evaluation that we often see is the use of Cross validation CV. Authors often report accuracy and other metrics (f-measure, precision,..etc) derived from this approach. Alongside that, they plot training and validation graphs for both loss and accuracy as well as confusion matrices. My question is about how these graphs are generated. Are they plotted using the k folds of cross-validation, or is there another method at play ? An example is in the paper in the link below : link to example
submitted by PerfecttMachine to MachineLearning [link] [comments]
2024.05.18 02:32 jps848384 Pharmacists to review their own professional titles after being accused of misleading patients
A pharmacy group will review its guidelines for pharmacists calling themselves registrars, residents and consultants after the AMA alleged that some patients had been misled.
The recently-launched Australian and New Zealand College of Advanced Pharmacy (ANZCAP) grants pharmacists these titles based on their pre-existing training and experience as part of its ‘foundation program’.
For example, pharmacists with over eight years’ general experience and three years’ experience in a specialty area can apply for recognition as ‘consultants’ and to use the postnominal ‘FANZCAP’.
More than 1600 pharmacists have been recognised so far, says the Society of Hospital Pharmacists of Australia (SHPA), which jointly set up the college in October 2023.
But the AMA said last week it had raised concerns with the pharmacy group over “the use of misleading titles by some hospital pharmacists … which may have confused patients”.
When asked by AusDoc, the AMA did not elaborate further.
A spokesperson for SHPA said it had been “unable to independently verify the misuse” of the terms.
However, they said the ANZCAP certificates of recognition (see below) would be revised so that ‘pharmacy’ or ‘pharmacist’ was “more prominently displayed.”
“In the interests of clarity and safety for health professionals and patients, SHPA has committed to an immediate review of ANZCAP guidelines around the use of terminology,” they added.
Separately, another pharmacy group has joined the AMA and a former RACGP president in voicing concern over pharmacists’ use of consultant or registrar titles.
ANZCAP’s template certificate of recognition.
The Victorian Directors of Pharmacy Group, which represents public hospital pharmacy directors, said in a statement it did not support pharmacists using the titles consultant or registrar at work.
“The use of the titles will be confusing to patients, the public and other health professionals and may not appropriately represent the expertise of the individual pharmacist,” it said.
It also called the ANZCAP assessment program, which costs pharmacists up to $595, an “expedited process through submission of letters of support and [a] CV without … evidence of level of practice”.
“The ANZCAP recognition is based primarily on length of time in practice and does not include a robust independent process of assessment of the individual’s level of practice,” it said.
The ANZCAP recognition is not recognised by the Pharmacy Board of Australia or the Australian Pharmacy Council.
https://www.ausdoc.com.au/news/doctors-concern-over-pharmacists-using-registrar-resident-and-consultant-titles-sparks-review/
submitted by jps848384 to ausjdocs [link] [comments]
The recently-launched Australian and New Zealand College of Advanced Pharmacy (ANZCAP) grants pharmacists these titles based on their pre-existing training and experience as part of its ‘foundation program’.
For example, pharmacists with over eight years’ general experience and three years’ experience in a specialty area can apply for recognition as ‘consultants’ and to use the postnominal ‘FANZCAP’.
More than 1600 pharmacists have been recognised so far, says the Society of Hospital Pharmacists of Australia (SHPA), which jointly set up the college in October 2023.
But the AMA said last week it had raised concerns with the pharmacy group over “the use of misleading titles by some hospital pharmacists … which may have confused patients”.
When asked by AusDoc, the AMA did not elaborate further.
A spokesperson for SHPA said it had been “unable to independently verify the misuse” of the terms.
However, they said the ANZCAP certificates of recognition (see below) would be revised so that ‘pharmacy’ or ‘pharmacist’ was “more prominently displayed.”
“In the interests of clarity and safety for health professionals and patients, SHPA has committed to an immediate review of ANZCAP guidelines around the use of terminology,” they added.
Separately, another pharmacy group has joined the AMA and a former RACGP president in voicing concern over pharmacists’ use of consultant or registrar titles.
ANZCAP’s template certificate of recognition.
The Victorian Directors of Pharmacy Group, which represents public hospital pharmacy directors, said in a statement it did not support pharmacists using the titles consultant or registrar at work.
“The use of the titles will be confusing to patients, the public and other health professionals and may not appropriately represent the expertise of the individual pharmacist,” it said.
It also called the ANZCAP assessment program, which costs pharmacists up to $595, an “expedited process through submission of letters of support and [a] CV without … evidence of level of practice”.
“The ANZCAP recognition is based primarily on length of time in practice and does not include a robust independent process of assessment of the individual’s level of practice,” it said.
The ANZCAP recognition is not recognised by the Pharmacy Board of Australia or the Australian Pharmacy Council.
https://www.ausdoc.com.au/news/doctors-concern-over-pharmacists-using-registrar-resident-and-consultant-titles-sparks-review/
2024.05.17 20:11 multi-chain Structure and Properties of Auxochromes
Structure and Properties of Auxochromes
Influence of Auxochromes on the Energy of π Orbitals of Benzene
Auxochromes are groups of atoms attached to a chromophore that modify the ability of that chromophore to absorb light. In benzene, auxochromes influence the energy levels of π orbitals through their electron-donating or electron-withdrawing properties. When an auxochrome is attached to benzene:- Electron-Donating Auxochromes: These groups (e.g., -OH, -NH₂) have lone pairs that can be delocalized into the π system of benzene, raising the energy of the π orbitals. This happens because the electron density is increased, making the π electrons more available for excitation.
- Electron-Withdrawing Auxochromes: These groups (e.g., -NO₂, -COOH) pull electron density away from the π system, lowering the energy of the π orbitals. This occurs because the electron density is decreased, making the π electrons less available for excitation.
Influence of Auxochromes on the Energy of Transition of the Absorption Bands
The energy required for electronic transitions in benzene changes significantly when auxochromes are present:- Bathochromic Shift (Red Shift): Electron-donating auxochromes can cause a bathochromic shift, which is a shift to longer wavelengths (lower energy). This happens because the auxochrome donates electron density into the conjugated system, stabilizing the excited state more than the ground state.
- Hypsochromic Shift (Blue Shift): Electron-withdrawing auxochromes cause a hypsochromic shift, which is a shift to shorter wavelengths (higher energy). This occurs because the auxochrome withdraws electron density, stabilizing the ground state more than the excited state, thus requiring more energy for the transition.
Why the Energy of the π Orbitals of Benzene Does Not Vary in the Same Way
The variation in energy of the π orbitals of benzene due to auxochromes depends on the specific electronic nature of the auxochrome. Electron-donating and electron-withdrawing groups have opposite effects on the electron density of the π system:- Electron-Donating Groups: Increase electron density in the π system, raising orbital energy levels.
- Electron-Withdrawing Groups: Decrease electron density in the π system, lowering orbital energy levels.
Influence of Auxochromes on the NMR Shielding Constant
The NMR shielding constant of a proton (or other nucleus) in benzene is influenced by the electron density around it. Auxochromes affect this electron density in the following ways:- Electron-Donating Auxochromes: These increase the electron density around the aromatic ring, leading to greater shielding of the protons. This results in a lower chemical shift (upfield shift) in the NMR spectrum.
- Electron-Withdrawing Auxochromes: These decrease the electron density around the aromatic ring, resulting in less shielding of the protons. This causes a higher chemical shift (downfield shift) in the NMR spectrum.
auxochromes significantly impact the electronic and spectroscopic properties of benzene by altering the energy levels of π orbitals, shifting the absorption bands, and modifying the NMR shielding constants, all of which depend on whether they donate or withdraw electron density from the aromatic system.
Diamagnetic Anisotropy and its Effects on the C=C Double Bond
1. Influence on Electron Distribution: Diamagnetic anisotropy significantly affects the electron distribution in a C=C double bond. The anisotropy arises because the π-electrons in the double bond generate a local magnetic field when subjected to an external magnetic field. This local field is non-uniform and creates regions of varying electron density around the double bond. The induced magnetic field tends to oppose the applied magnetic field within certain regions, leading to areas of shielding and deshielding.2. Shielding Zones and Deshielding Cones:
In the context of a C=C double bond:- Shielding Zones: These are regions where the local magnetic field created by the circulating π-electrons opposes the applied magnetic field, leading to a decrease in the effective magnetic field experienced by nuclei in these regions. Typically, positions directly above and below the plane of the double bond are shielded due to the circulation of π-electrons.
- Deshielding Cones: These are regions where the local magnetic field enhances the applied magnetic field, increasing the effective magnetic field experienced by nuclei in these regions. The regions adjacent to the plane of the double bond, along the axis of the bond, are deshielded due to the same π-electron circulation.
- Longitudinal Currents: These occur along the axis of the double bond.
- Transverse Currents: These are perpendicular to the plane of the double bond.
5. Influence on the NMR Spectrum: Diamagnetic anisotropy significantly impacts the NMR spectrum of molecules containing C=C double bonds. The key effects include:
- Chemical Shift: The anisotropic effects of the π-electrons lead to characteristic shifts in the NMR signals of protons or other nuclei near the C=C bond. Protons in the shielding zone (above or below the double bond) experience an upfield shift (lower chemical shift), while those in the deshielding cone (adjacent to the bond plane) experience a downfield shift (higher chemical shift).
- Signal Splitting: The induced magnetic fields can cause splitting of the NMR signals if multiple protons are differentially affected by the shielding and deshielding effects.
Example from Literature
For instance, the shielding and deshielding effects due to diamagnetic anisotropy explain why the protons in alkene and aromatic compounds have distinct chemical shifts. In benzene, the ring current effect, a type of diamagnetic anisotropy, leads to significant deshielding of the protons on the ring, resulting in a downfield shift in the NMR spectrum .These principles help in interpreting NMR spectra and understanding the electronic environment of molecules, particularly those with conjugated π-systems such as alkenes and aromatic compounds.
Let’s delve into the detailed explanations of the concepts you asked about: diamagnetic anisotropy, the Cotton effect, and NMR analysis of racemic mixtures.
Diamagnetic Anisotropic Shielding Constant
Diamagnetic anisotropy refers to the direction-dependent response of a molecule’s electrons to an applied magnetic field. This concept is particularly relevant in NMR spectroscopy, where it influences the chemical shifts observed in different types of protons or carbons within a molecule.- Influence on Electron Distribution: In a C=C double bond, the π-electrons are able to circulate more freely compared to σ-electrons. When an external magnetic field is applied, these π-electrons generate a secondary magnetic field. If the molecule is oriented such that the π-electrons circulate perpendicular to the applied field, they generate a shielding effect for the protons along the axis of the applied field.
- Shielding and Deshielding Zones:
- Shielding zones are areas where the induced magnetic field opposes the external field, thus reducing the overall magnetic field experienced by the nucleus, leading to an upfield shift (lower chemical shift).
- Deshielding cones are regions where the induced field adds to the external field, increasing the magnetic field experienced by the nucleus, leading to a downfield shift (higher chemical shift)【21:0†source】【21:2†source】.
- Induced Currents: In a C=C double bond, the circulation of π-electrons in response to the external magnetic field generates these induced currents. The longitudinal induced currents (along the length of the bond) usually prevail in creating the anisotropic effect.
- NMR Spectrum Impact: Due to diamagnetic anisotropy, protons in the deshielding zone of a C=C bond (typically the vinylic protons) will experience a downfield shift, whereas protons in the shielding zone (e.g., protons adjacent to a triple bond) will experience an upfield shift【21:2†source】.
Cotton Effect
The Cotton effect is an important phenomenon in chiroptical spectroscopy and refers to the differential absorption of left and right circularly polarized light in the vicinity of an absorption band, resulting in circular dichroism.- Measurement and Interpretation: The Cotton effect can be observed as positive (when left circularly polarized light is absorbed more than right) or negative (when right is absorbed more than left). This effect provides information about the absolute configuration of chiral molecules and their electronic transitions.
- Effect of Substituent Position: The position of substituents on a chiral center can significantly alter the magnitude and sign of the Cotton effect. Substituents influence the electronic environment and thus the differential absorption of circularly polarized light.
- Equatorial Substituents: Substituents in the equatorial position generally have a more pronounced effect on the Cotton effect compared to axial substituents due to their spatial orientation and electronic interactions with the chiral center【21:4†source】.
NMR Analysis of Racemic Mixtures
In NMR spectroscopy, racemic mixtures (equal mixtures of enantiomers) present unique challenges and opportunities:- Chiral Solvating Agents (CSAs): Using chiral solvents or chiral additives can induce chemical shift differences between enantiomers, allowing for their differentiation in the NMR spectrum.
- Diastereotopic Proton Splitting: Near a chiral center, protons that are diastereotopic (non-equivalent in a chiral environment) will show distinct chemical shifts. This can be exploited to analyze the ratio and configuration of enantiomers.
- Enantiomeric Excess Determination: By integrating the areas under NMR peaks corresponding to each enantiomer, the enantiomeric excess (ee) can be determined. This is crucial for assessing the purity and yield of chiral compounds in asymmetric synthesis【21:4†source】.
Stability of Stable and Metastable Ions in Mass Spectrometry
Criteria for Stability:- Thermodynamic Stability: Stable ions have low internal energy and are less likely to fragment.
- Kinetic Stability: Metastable ions have higher internal energy but do not immediately fragment; they require additional energy input or time to do so.
- Resonance Stabilization: Ions with delocalized charge, such as aromatic ions, tend to be more stable.
- Hyperconjugation and Inductive Effects: These effects stabilize the charge by distributing it over a larger volume or through sigma bonds.
- Stable ions have lower fragmentation energy, meaning they are less likely to break apart.
- Metastable ions have higher fragmentation energy, indicating they are more prone to fragmentation under specific conditions.
Types of Fragmentation in Mass Spectrometry
- Homolytic Cleavage: Produces a radical cation and a neutral radical. This involves the equal splitting of a bond where each fragment takes one electron.
- Heterolytic Cleavage: Results in a cation and a neutral molecule, where the bond electrons move together to one fragment.
- Alpha Cleavage: Common in carbonyl compounds, where the bond adjacent to the functional group is cleaved.
- McLafferty Rearrangement: Specific to compounds with gamma hydrogens relative to a carbonyl group, leading to a transfer of hydrogen and cleavage.
- Retro-Diels-Alder Reaction: Common in cyclic compounds, where a six-membered ring splits into two smaller fragments.
Karplus Equation in NMR Spectroscopy
The Karplus equation relates the vicinal proton-proton coupling constant ((J)) to the dihedral angle ((\phi)) between the protons: [ J = A + B \cos(\phi) + C \cos(2\phi) ] where (A), (B), and (C) are empirical constants specific to different types of vicinal coupling.Influence of Inductive and Mesomeric Effects on Chemical Shifts in Alpha-Keto Compounds
- Inductive Effect: Electronegative atoms or groups withdraw electron density through sigma bonds, increasing deshielding and leading to downfield chemical shifts of alpha protons.
- Mesomeric (Resonance) Effect: Electron-donating groups can delocalize electron density through pi bonds, leading to upfield shifts (shielding) of alpha protons.
Bipolar Field Effect vs. Inductive Effect
- Bipolar Field Effect: Involves the overall electron distribution around a molecule, particularly in the presence of multiple polar substituents, influencing the chemical environment.
- Inductive Effect: A localized effect where electron-withdrawing or donating groups influence nearby atoms through sigma bonds.
Chetoenic Effect in Cyclohexanone
- Chetoenic Tautomerism: The keto-enol tautomerism can influence NMR chemical shifts by altering electron density around protons.
- Configuration Determination: The axial or equatorial position of substituents can be inferred from the chemical shift changes due to the different electronic environments.
Stability and Fragmentation in Mass Spectrometry
Criteria for Stability:- Thermodynamic and Kinetic Stability: Stable ions have low internal energy; metastable ions have higher energy but do not immediately fragment.
- Resonance and Hyperconjugation: Stabilize the ion by delocalizing charge.
- Homolytic and Heterolytic Cleavage: Homolytic produces radical cations and neutral radicals; heterolytic results in cations and neutral molecules.
- Specific Fragmentations: Alpha cleavage and McLafferty rearrangement involve characteristic bond cleavages and hydrogen transfers.
- Relates vicinal coupling constants to dihedral angles in NMR, aiding in conformational analysis.
- Inductive Effect: Electronegative groups deshield alpha protons.
- Mesomeric Effect: Electron-donating groups can shield protons.
- Involves overall electron distribution, affecting the chemical shift differently than the inductive effect.
- Tautomerism can be used to determine the axial or equatorial positions of substituents in cyclohexanone based on NMR shifts.
Alpha-Alketo Compounds as Indicators in Spectroscopic Techniques
Alpha-alketo compounds are often used in spectroscopic techniques due to their characteristic absorption properties. These compounds contain a carbonyl group adjacent to an alkene, making them useful in various spectroscopic analyses such as UV-Vis and NMR spectroscopy.Influence of Bromine Atom Position on UV-Vis Spectrum
The presence of a bromine atom in an alpha-alketo compound significantly affects its UV-Vis spectrum. Whether the bromine is in the axial or equatorial position can influence the electronic environment around the carbonyl group. Generally, bromine, being a heavy atom with significant electron-withdrawing capabilities, can induce changes in the absorption maxima (λ_max) of the compound:- Axial Position: Bromine in the axial position may cause less steric hindrance, potentially leading to a slightly higher energy absorption due to less stabilization.
- Equatorial Position: Bromine in the equatorial position might cause more steric hindrance and thus stabilize the molecule more, potentially leading to a lower energy absorption (bathochromic shift).
Overlap of p Orbitals and Sigma* Orbitals
The overlap of the p orbitals of the carbonyl group and the σ* (sigma star) orbitals of the adjacent carbon influences the UV-Vis spectrum of alpha-alketo compounds. This interaction, known as hyperconjugation, can lead to:- Stabilization of the Transition State: This overlap allows delocalization of electrons, lowering the energy required for electronic transitions and thus leading to a bathochromic shift (shift to longer wavelengths).
- Increased Absorption Intensity: The transition involving π to π* (pi to pi star) transitions becomes more allowed, increasing the intensity of absorption bands.
Determinants of Bathochromic Shift
The bathochromic shift in the UV-Vis spectrum of alpha-alketo compounds can be influenced by several factors:- Conjugation: Increased conjugation with the carbonyl group leads to a delocalization of electrons, resulting in a lower energy transition and a shift to longer wavelengths.
- Substituents: Electron-donating groups (EDGs) attached to the conjugated system can further stabilize the excited state, causing a bathochromic shift.
- Solvent Effects: Polar solvents can stabilize the ground and excited states differently, leading to shifts in absorption maxima.
Example Analysis Using UV-Vis Spectroscopy
Consider an alpha-alketo compound with a bromine substituent. When analyzing its UV-Vis spectrum:- Identify λ_max: Determine the absorption maxima.
- Compare Axial vs. Equatorial: Assess any shifts in λ_max due to the position of bromine.
- Look for Hyperconjugation Effects: Evaluate changes in intensity and wavelength due to p orbital and σ* orbital overlap.
How Alpha-Alkyl Ketones are Used in 1H NMR Spectroscopy
Alpha-alkyl ketones (α-alkyl ketones) are significant in 1H NMR spectroscopy because they provide distinctive signals for protons adjacent to the carbonyl group. These protons (α-protons) are deshielded due to the electron-withdrawing nature of the carbonyl group, which generally causes their chemical shifts to appear downfield (at higher ppm values) compared to typical alkyl protons.Influence of Vicinal Coupling Constant (J) on the 1H NMR Spectrum
The vicinal coupling constant (J) represents the interaction between protons on adjacent carbon atoms (three bonds apart). For α-alkyl ketones, the J value affects the splitting patterns of the α-protons. Typically, vicinal coupling constants for such protons in a standard alkyl chain are in the range of 6-8 Hz. In the context of α-alkyl ketones, the deshielding by the carbonyl group might slightly modify these values:- Higher J values: Can indicate rigid structures or interactions through double bonds or rings.
- Lower J values: Suggest more flexible structures or reduced electron density around the intervening bonds.
Distinguishing Axial and Equatorial Protons Using 1H NMR Spectroscopy
In cyclic ketones like cyclohexanone derivatives, protons can occupy axial or equatorial positions. These positions significantly influence their NMR chemical shifts due to different spatial environments and magnetic anisotropies:- Axial Protons: Typically appear at different chemical shifts compared to equatorial protons due to the ring’s anisotropic effects. Axial protons are usually more deshielded because they are aligned with the ring current, leading to higher ppm values.
- Equatorial Protons: Experience less deshielding and are more shielded than axial protons, resulting in lower ppm values.
Example: Cyclohexanone Derivatives
In cyclohexanone, rapid chair flipping usually averages the chemical environments of axial and equatorial protons. However, substituents can slow down this flipping, allowing separate observation of axial and equatorial proton signals in the NMR spectrum.- Temperature Dependence: At lower temperatures, chair flipping slows, and distinct signals for axial and equatorial protons can be observed.
- Substituent Effects: Large or polar substituents can create significant differences in chemical shifts between axial and equatorial protons.
1H NMR spectroscopy of α-alkyl ketones reveals important information about the chemical environment and spatial arrangement of protons. The chemical shifts of α-protons are influenced by the electron-withdrawing effect of the carbonyl group, and the vicinal coupling constants provide details on the interactions between neighboring protons. Distinguishing between axial and equatorial protons in cyclic structures further enhances our understanding of the molecule’s 3D structure. These insights are crucial for interpreting the NMR spectra and determining the detailed structure of α-alkyl ketones.
Influence of Field-Dipole Effects on the Vibrational Frequency of the C=O Bond in Alpha-Alketones
Field-Dipole Effects
The field-dipole effect arises from the interaction of the electric field generated by the dipole moments of substituents with the vibrational motion of the C=O bond. This effect can either increase or decrease the vibrational frequency of the C=O bond depending on the nature and orientation of the dipole relative to the bond.In alpha-alketones, the presence of a substituent with a strong dipole moment can affect the electron density around the carbonyl group, thus influencing its vibrational frequency. For example, an electronegative substituent like bromine can withdraw electron density through its inductive effect, increasing the partial positive charge on the carbonyl carbon and thereby increasing the force constant of the C=O bond, which results in a higher vibrational frequency.
Difference in Vibrational Frequency between Alpha-Alketones with Bromine in Axial and Equatorial Positions
The vibrational frequency of the C=O bond in alpha-alketones can differ significantly depending on whether a bromine atom is in the axial or equatorial position. This difference is not solely explained by the field-dipole effect. When bromine is in the axial position, there is greater steric hindrance and potential electronic interactions with the neighboring hydrogen atoms in the 1,3-diaxial positions. These interactions can increase the vibrational frequency by increasing the rigidity of the molecule and reducing the bond length slightly.In contrast, when bromine is in the equatorial position, the steric hindrance is minimized, and the molecule is generally more relaxed, resulting in a lower vibrational frequency for the C=O bond. This illustrates that steric effects and electronic interactions beyond the simple field-dipole effect play significant roles.
Distinguishing Field-Dipole Effects from Inductive Effects
To distinguish between field-dipole effects and inductive effects in alpha-alketones, one must consider the nature and magnitude of the shifts in vibrational frequencies:- Field-Dipole Effects: These primarily arise from the orientation and strength of the dipole moments of the substituents. They tend to cause shifts that are more directionally dependent. For instance, changing the position of a substituent like bromine from axial to equatorial can significantly alter the vibrational frequency due to changes in the spatial arrangement of dipoles.
- Inductive Effects: These are due to the electron-withdrawing or electron-donating properties of the substituents through sigma bonds. Inductive effects are usually less sensitive to the spatial orientation of the substituent and more related to the nature of the substituent itself. For example, replacing a hydrogen with a bromine atom will generally increase the vibrational frequency of the C=O bond due to the
- Field-dipole effects influence the vibrational frequency of the C=O bond based on the orientation and strength of the dipole moments of substituents.
- The difference in vibrational frequency for alpha-alketones with bromine in axial versus equatorial positions is not solely explained by field-dipole effects but also involves steric and electronic interactions.
- To distinguish field-dipole effects from inductive effects, one must consider the directionality and the nature of the substituent. Inductive effects are more related to the electron-withdrawing or donating nature, while field-dipole effects are more influenced by the spatial arrangement of substituents.
2024.05.17 16:15 aidforsoft Do you expose your Leetcode efforts to potential employers?
For example, do you have a link to your Leetcode profile in your CV or on a LinkedIn page? And if you do, does it make any difference?
submitted by aidforsoft to leetcode [link] [comments]
2024.05.17 14:43 SolitarySoundGuy Patch share - NNXT String Ensemble
https://preview.redd.it/loh5owl7az0d1.png?width=1920&format=png&auto=webp&s=822b140f0d6ccc4ec0b913cbe7e3d54e48a5330c
Good afternoon everyone.
I made a fairly comprehensive string ensemble combinator with my own samples and wanted to see if anyone fancied a go with it. The initial samples actually play like a braam and have a lot of impact, yet for my initial patch i let out the release and gave it a slow attack so it plays a short sustain that works well with chords. Each sample is actually multiple samples recorded with varying attack and release times to give a great sense of depth, similiar to that of a real ensemble where every player will have different timings and which amount to a grandiose feel (there is a term for this but i've forgotton it). I've built in a large amount of FX modulation with an emphasis on sample freezing and pitch modulation, but there's a lot going on behind the scenes, some of the devices are used to shape the depth of the sounds with CV modulation. For example Europa is used to keytrack the X-Over on a stereo imager. The total file size is about 50mb (uncompressed) and i've sampled 49 keys from C0. The polar dual pitch shifter is needed for the pitch shifting effect, but if you dont have it then you'll still be able to play the ensemble, and if you don't have Reason 12 i've included the NNXT preset and sample folder, when you load it you just need to tell the NNXT where the samples are and it'll auto-map. If anyone's interested i can share a we transfer link and record a video explaining everything in more detail. This is fantastic for experimental sound design and translates well with other NNXT patches as well.
EDIT: Here's the download link, if you need an explanation let me know.
https://we.tl/t-5qlOE9xZ9E
submitted by SolitarySoundGuy to reasoners [link] [comments]
Good afternoon everyone.
I made a fairly comprehensive string ensemble combinator with my own samples and wanted to see if anyone fancied a go with it. The initial samples actually play like a braam and have a lot of impact, yet for my initial patch i let out the release and gave it a slow attack so it plays a short sustain that works well with chords. Each sample is actually multiple samples recorded with varying attack and release times to give a great sense of depth, similiar to that of a real ensemble where every player will have different timings and which amount to a grandiose feel (there is a term for this but i've forgotton it). I've built in a large amount of FX modulation with an emphasis on sample freezing and pitch modulation, but there's a lot going on behind the scenes, some of the devices are used to shape the depth of the sounds with CV modulation. For example Europa is used to keytrack the X-Over on a stereo imager. The total file size is about 50mb (uncompressed) and i've sampled 49 keys from C0. The polar dual pitch shifter is needed for the pitch shifting effect, but if you dont have it then you'll still be able to play the ensemble, and if you don't have Reason 12 i've included the NNXT preset and sample folder, when you load it you just need to tell the NNXT where the samples are and it'll auto-map. If anyone's interested i can share a we transfer link and record a video explaining everything in more detail. This is fantastic for experimental sound design and translates well with other NNXT patches as well.
EDIT: Here's the download link, if you need an explanation let me know.
https://we.tl/t-5qlOE9xZ9E
2024.05.17 14:15 Ill-Balance-3117 Taking a lower title or level for FAANG experience
I've been working in software engineering for the past seven years, with a 'senior' title for the past four years. I've been given a lot of responsibility and been put in positions where I've had to make architectural/design decisions and live/learn from the consequences. All this has been in smaller companies though, and I've had an itch to get FAANG experience on my CV.
I've talked to friends who worked in big tech companies, and they've mentioned how the brand identity of their employer leads to a surge of interest from recruiters who are literally just searching for people who have worked at specific companies. All that to say, it seems like the brand recognition does add value to your CV, and I'm willing to put in the time to grind away at the necessary interview prep.
Looking at Google, for example, their current openings show a really relevant engineering role that's listed as 'early' career, and some technical solutions engineering roles that are listed as 'mid' career. In this hypothetical scenario where I applied and got an offer for a job with a lower level/role than my current one, I'm curious if it the brand recognition of a company like Google would outweigh the optics of losing the level of seniority that I have now?
For example, I could potentially have a Principal title in my current place in the next few years (in a company that's not well known). If there was the option to take an L3 role at Google, would the eternal 'ex-Google' brand benefit me more in the long run? Similarly, I have a lot of responsibility now, but if I was (hypothetically) offered an L4 Solution Engineering role in Google, would that benefit me more in the long run?
I realise that there's no perfect answer here, just curious to gauge the opinions of others. Cheers!
submitted by Ill-Balance-3117 to DevelEire [link] [comments]
I've talked to friends who worked in big tech companies, and they've mentioned how the brand identity of their employer leads to a surge of interest from recruiters who are literally just searching for people who have worked at specific companies. All that to say, it seems like the brand recognition does add value to your CV, and I'm willing to put in the time to grind away at the necessary interview prep.
Looking at Google, for example, their current openings show a really relevant engineering role that's listed as 'early' career, and some technical solutions engineering roles that are listed as 'mid' career. In this hypothetical scenario where I applied and got an offer for a job with a lower level/role than my current one, I'm curious if it the brand recognition of a company like Google would outweigh the optics of losing the level of seniority that I have now?
For example, I could potentially have a Principal title in my current place in the next few years (in a company that's not well known). If there was the option to take an L3 role at Google, would the eternal 'ex-Google' brand benefit me more in the long run? Similarly, I have a lot of responsibility now, but if I was (hypothetically) offered an L4 Solution Engineering role in Google, would that benefit me more in the long run?
I realise that there's no perfect answer here, just curious to gauge the opinions of others. Cheers!
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2024.05.17 10:24 aussiegolfer New Map: Longest Road of Every Country
Hi all, me and my friends have made a new map that we thought had a cool concept: the longest road of every country that has streetview! Some roads are long boring highways, some roads are cool mountainous-region-crossing spaghetti strands, and some are in between. We'd love if you gave it a go and let us know what you think!
Some notes: if the road has the same label on google maps we considered it as the same road (for example E-roads in Europe or the AH2 in Thailand). If a road is "known" we considered it as the same road (for example the Trans-Siberian Highway, or the Monaco Formula 1 circuit). To work out the number of locations we took the square root of the road length, so Australia's 14,500km ring road has 121 locations, and we gave the smallest roads a floor of 5 locations so they would have some representation.
In the map description is a google docs link that has the names of all contributors, thank you to them for the work choosing the locations!
Here's the link, and a few challenge links! https://www.geoguessr.com/maps/6646031fd4341f057412efcc https://www.geoguessr.com/challenge/NVfr75RDUotCvSuc?c=aussiegolfer moving https://www.geoguessr.com/challenge/uOAXhhHC4IkElBC9?c=aussiegolfer no moving https://www.geoguessr.com/challenge/7hWRlG74BNwo8WE4?c=aussiegolfer no moving panning or zooming
submitted by aussiegolfer to geoguessr [link] [comments]
Some notes: if the road has the same label on google maps we considered it as the same road (for example E-roads in Europe or the AH2 in Thailand). If a road is "known" we considered it as the same road (for example the Trans-Siberian Highway, or the Monaco Formula 1 circuit). To work out the number of locations we took the square root of the road length, so Australia's 14,500km ring road has 121 locations, and we gave the smallest roads a floor of 5 locations so they would have some representation.
In the map description is a google docs link that has the names of all contributors, thank you to them for the work choosing the locations!
Here's the link, and a few challenge links! https://www.geoguessr.com/maps/6646031fd4341f057412efcc https://www.geoguessr.com/challenge/NVfr75RDUotCvSuc?c=aussiegolfer moving https://www.geoguessr.com/challenge/uOAXhhHC4IkElBC9?c=aussiegolfer no moving https://www.geoguessr.com/challenge/7hWRlG74BNwo8WE4?c=aussiegolfer no moving panning or zooming
2024.05.17 09:59 sinomaltanews Editorial: Engaging young people in politics
https://timesofmalta.com/article/editorial-engaging-young-people-politics.1092521?utm_medium=Social&utm_source=Facebook&fbclid=IwZXh0bgNhZW0CMTEAAR2lTbteGeF5zi-JVabNVOL47cqRbXn6Ak-cVVkkXsaupnTXsGbYeMeF3Vk_aem_AQ1Q66x82NPTUsktdH-NrhGjFQOk7A1h_t2YR410TXmOBgiY0pIWSwZEJ3X6BtUiGMcCvB78GyQ3crmrbVSPiGfe#Echobox=1715929616
As the leader of the Malta Catholic Democratic Party, I would like to address the concerns raised in the recent editorial published by the Times of Malta regarding the disengagement of young people from political life1.
Statement:
The Malta Catholic Democratic Party acknowledges the findings of various international studies and the most recent Eurobarometer survey, which highlight a troubling trend of disengagement among our youth in the political process1. It is a matter of great concern that nearly one in three young Maltese under 30 are hesitant to participate in the upcoming European Parliament elections1.
We believe that the heart of democracy lies in the active participation of its citizens, especially the younger generation who are the future leaders of our nation. The issues raised, such as climate change, socio-economic inequality, and the need for a more responsive government, resonate deeply with our party’s values and mission1.
Our party is committed to bridging the gap between policymakers and young citizens. We understand that while our country enjoys full employment, this does not automatically translate into political engagement or satisfaction with the democratic process1. We must listen to the voices of our youth, understand their concerns, and act upon them.
We are inspired by the 45% of young Maltese who have taken action to change society over the past year1. This shows that our youth are not apathetic but are seeking alternative avenues to express their political will and make a difference.
The Malta Catholic Democratic Party is dedicated to creating platforms for dialogue and action where young people can meaningfully contribute to policy debates and the democratic process. We will work tirelessly to ensure that the concerns of young people are not only heard but are also at the forefront of our political agenda.
We call upon all young Maltese to join us in this endeavor to strengthen our democracy and shape a future that aligns with our shared values and aspirations.
Together, we can build a Malta that truly reflects the hopes and dreams of its youngest citizens.
End of Statement
It is crucial for political parties to not only recognize the issues but also to take concrete steps towards involving young people in the political discourse, ensuring their voices are heard and their concerns addressed. The Malta Catholic Democratic Party stands ready to lead by example in this regard.
submitted by sinomaltanews to MCDP [link] [comments]
As the leader of the Malta Catholic Democratic Party, I would like to address the concerns raised in the recent editorial published by the Times of Malta regarding the disengagement of young people from political life1.
Statement:
The Malta Catholic Democratic Party acknowledges the findings of various international studies and the most recent Eurobarometer survey, which highlight a troubling trend of disengagement among our youth in the political process1. It is a matter of great concern that nearly one in three young Maltese under 30 are hesitant to participate in the upcoming European Parliament elections1.
We believe that the heart of democracy lies in the active participation of its citizens, especially the younger generation who are the future leaders of our nation. The issues raised, such as climate change, socio-economic inequality, and the need for a more responsive government, resonate deeply with our party’s values and mission1.
Our party is committed to bridging the gap between policymakers and young citizens. We understand that while our country enjoys full employment, this does not automatically translate into political engagement or satisfaction with the democratic process1. We must listen to the voices of our youth, understand their concerns, and act upon them.
We are inspired by the 45% of young Maltese who have taken action to change society over the past year1. This shows that our youth are not apathetic but are seeking alternative avenues to express their political will and make a difference.
The Malta Catholic Democratic Party is dedicated to creating platforms for dialogue and action where young people can meaningfully contribute to policy debates and the democratic process. We will work tirelessly to ensure that the concerns of young people are not only heard but are also at the forefront of our political agenda.
We call upon all young Maltese to join us in this endeavor to strengthen our democracy and shape a future that aligns with our shared values and aspirations.
Together, we can build a Malta that truly reflects the hopes and dreams of its youngest citizens.
End of Statement
It is crucial for political parties to not only recognize the issues but also to take concrete steps towards involving young people in the political discourse, ensuring their voices are heard and their concerns addressed. The Malta Catholic Democratic Party stands ready to lead by example in this regard.
2024.05.17 05:27 HumorAccomplished252 State govt job employment checks
Hi Tassie people
I'm considering applying for a Tas gov job, and I notice they mention if you're offered a job you need to a 'previous disciplinary action in past job' check as well as usual criminal history etc.
Can anyone elucidate what this is and how it's done.
Basically I'm just thinking about what past jobs to include on my CV, I've never had past work disciplinary action and all my past employers will say I was a good boy, but if I have to send each of my past employers some form to fill out then I'd rather just axe several of my old roles from my CV - do they just go off your CV, or do they require you to for example list every job you've had in the past 10 years when they ask to do the check?
Thanks for any insight !
submitted by HumorAccomplished252 to tasmania [link] [comments]
I'm considering applying for a Tas gov job, and I notice they mention if you're offered a job you need to a 'previous disciplinary action in past job' check as well as usual criminal history etc.
Can anyone elucidate what this is and how it's done.
Basically I'm just thinking about what past jobs to include on my CV, I've never had past work disciplinary action and all my past employers will say I was a good boy, but if I have to send each of my past employers some form to fill out then I'd rather just axe several of my old roles from my CV - do they just go off your CV, or do they require you to for example list every job you've had in the past 10 years when they ask to do the check?
Thanks for any insight !